A probe into the literature survey clearly reveals no work has been carried out for the synthesis of (E)-2-(2, 6-dichlorobenzylidene)hydrazinecarbothioamide (DHC)using 2,6-dichlorobenzaldehyde and thiosemicarbazide. Aim and scope of the work is highly effective medicinal hydrazide derivative has been synthesized from Schiff base route and also synthesized its some transition metal complexes. The structure of the ligand DHC and its complexes were carried various spectral studies. From these studies, I know about the knowledge of organic chemistry and spectroscopy. In my present work, we have to synthesis of (E)-2-(2, 6-dichloro benzylidene) hydrazinecarbothioamide and establish the structure through the analytical (elemental and TLC) and spectral (IR, H 1 NMR and C 13 NMR) methods of characterization.